The
commonly used molding materials are mainly composed of resin matrix,
reinforcing materials, fillers, pigments, etc., and according to the process
and performance requirements, the resin matrix is also added with curing agent,
thickener, internal release agent, solvent and other additives. Reinforcement
material is the skeleton material of die pressing material, which mainly endows
die pressing material with excellent mechanical properties and prevents the
propagation of micro-cracks. The main varieties of reinforcement materials are
various glass fiber felt, no twist roving, no twist coarse gauze, chopped
fiber, ground fiber, glass yarn and fabric and other varieties of fiber. The
main function of resin matrix in molding material is to bond the reinforcing
material and filler together, which not only protects the reinforcing material,
but also makes it uniform force under external load. Theoretically, most types
of thermoplastic and thermosetting resins can be used as resin matrix
materials. There are polyester resin, epoxy resin, amino resin and phenolic
resin. A large number of various types of fillers are used in the molding
material, the main function of which is to reduce the material cost, improve
the process, improve the molding material some physical properties, appearance
and give some characteristics. Fillers are mostly in powder form, such as clay,
calcium carbonate, talcum powder and some fillers with special performance
requirements.
The
basic requirements of resin in molding are as follows: good infiltration performance
of reinforcing materials and fillers to improve the bonding strength between
resin and glass fiber; Resin to have the appropriate: viscosity, good fluidity,
so that in the molding process of resin and glass fiber at the same time full
of all corners of the cavity, to obtain a balanced strength of the molding
products; Resin curing temperature is low, less volatile in the curing process,
good technology (such as viscosity easy to adjust, good solubility with various
solvents, easy to release mold, etc.), and can meet the mold products specific
performance requirements. In addition, from the point of view of application or
other point of view, the resin should also meet some other special performance
requirements, such as corrosion resistance, heat resistance and so on. From the
perspective of production efficiency, fast curing speed of resin is required,
but for some large products with complex structure and higher requirements, the
curing speed should be properly controlled. Resin curing after high mechanical
strength, good toughness, avoid from the mold when taken out, in the case of
bending cracking or breaking. Therefore, the selection of resin, will become a
very important factor affecting the whole process.
Molding products are commonly used in thermosetting resin, thermoplastic resin in the
molding process of the application of less. The main thermosetting resins are
phenolic resin, epoxy resin, epoxy phenolic resin, polyvinyl butanal resin,
unsaturated polyester resin, etc.
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