The forming process of the PTFE pipe has a
pressing method, an extrusion method, a hydraulic method, a welding method, a
winding method, and the like, and the pressing method is mainly used.
Generally, a dispersed PTFE resin having a particle diameter of 500 μm and an
apparent density of 0.45 g/ml to 0.55 g/ml is used. The small diameter tube is
made of a resin with a relatively large compression, and the large and medium
diameter tube is made of a resin with a relatively small compression. The
propellant is usually selected from solvent oils No. 200 and No. 260. The PTFE
pipe is subjected to secondary processing to obtain a PTFE heat shrinkable
pipe, a PTFE spiral pipe, a PTFE steel wire reinforced hydraulic pipe, and the
like.
1.1,
Teflon ordinary tube
The Teflon common tube is made by pressing
a polytetrafluoroethylene dispersion resin at a normal temperature with an
organic solvent as a squeezing agent, and then drying and sintering. According
to the size of the pipe diameter, it can be divided into two types: ordinary
pipe and micro pipe. Ordinary tube inner diameter > 4mm, micro tube inner
diameter ≤ 4mm.
Typical
formulations for the production of PTFE tubes:
Dispersed
PTFE resin: 100 parts by weight
Squeezing
agent: 18~24
Production
process:
PTFE,
squeezing agent → mixing → pressing → drying → sintering → cooling → product.
Production
process parameters:
Mixing:
Temperature ≤19 °C, time 10min~20min, mixing at 25 °C ~ 30 °C for more
than 24h.
Billet:
The compression rate is about 50mm/min and the pressure is 0~3MPa.
Pushing:
the temperature of the cavity is 30 °C ~ 50 °C, the die temperature is 50 °C ~
60 °C, the pushing rate becomes smaller with the increase of the pipe diameter,
and accelerates as the wall thickness becomes smaller.
Drying:
below 210 °C, 2h~3h
Sintering:
batch sintering, heating rate 60 °C / h, 375 °C ± 5 °C for 4h.
Continuous sintering, drying zone 100 °C ~
250 °C, preheating zone 250 °C ~ 330 °C, sintering zone 380 °C ~ 420 °C,
cooling zone less than 300 °C.
Main
equipment: mixer, pre-former, vertical pusher, drying and sintering furnace.
Uses: as insulation and conveying fluid
conduits.
1.2,
Teflon heat shrinkable tube
The PTFE
heat shrinkable tube has the property of being heat-shrinked, so it can be
tightly coated on the surface of other workpieces, making the workpiece
corrosion-resistant, electrically insulating and anti-adhesive. Widely used in
electrical, chemical, mechanical, printing and other industries. The maximum
shrinkage of PTFE heat shrink tubing is reported to be greater than 75%.
Made of
dispersed PTFE resin, the principle is that PTFE is subjected to stress during
processing to produce forced high elastic deformation. This deformation is
reversible, and the low temperature makes it freeze. If reheated and frozen,
the forced high elastic deformation will gradually disappear and Revert to the
original state.
Typical
formulations for the production of PTFE heat shrink tubing:
Dispersed
PTFE resin 100 (parts by weight)
Squeezing agent 20~22
Production process:
PTFE resin, extrusion aid → mixing → storage → preforming → pressing → drying → sintering → cooling → heat
treatment → inflation → cooling → product.
Production process parameters:
The front part is the same as a normal PTFE
tube.
Heat treatment: The process of quenching
the dried and sintered pipe again after further sintering at a high temperature
again, the temperature is 390 °C ± 2 °C, and the coolant is - 5 °C.
Inflation: At about 310 °C, it is filled
with a compressed gas of 0198 MPa or less, and the inflation rate is 200% to
400%.
Main equipment: Inflator, the other is the
same as ordinary PTFE
tube.
1.3, PTFE steel wire reinforced hydraulic
pipe
The
ordinary PTFE tube will be ruptured under the pressure of about 40kg/cm2. When
it is combined with the steel wire, the pressure resistance is greatly
improved, and the maximum working pressure in foreign countries reaches
700kg/cm2. Studies have shown that the compressive strength and pulse strength
of the hose are not only related to the strength of the steel wire, but also to
the size of the braiding angle. When the weaving angle of the single layer
weaving is 54° 44′′, the steel wire does not elongate under the internal pressure, and
the length and diameter of the hose do not change, and the pressure resistance
is the best.
When used as a hose for aerospace
industrial hydraulic systems, in order to prevent static breakdown of the inner
tube due to the flow of hydraulic oil, a small amount of conductive carbon
black must be added during the manufacture of the PTFE inner tube. However,
studies have found that the addition of carbon black does not completely
prevent static electricity from discharging through the tube wall and increases
voids.
In the
1960s, Attas manufactured a composite tube, in which the inner layer of the
tube was a uniform mixture of conductive carbon black and PTFE, and the outer
layer of the tube was pure PTFE. This form of inner tube layer has axial
electrical conductivity, so it can remove static electricity and prevent
seepage.
Its
process:
Inner
layer resin (including conductive carbon black), outer layer resin → compact → push → dry → cooling → inspection → weaving → fitting → inspection.
PTFE
steel wire composite hoses are mainly used in hydraulic systems,
air-conditioning systems, fuel systems, and oil systems on aircraft. In the
civil industry, it is suitable for rubber, plastic, pharmaceutical, clothing,
shipbuilding, automotive, machine tools, motors, diesel, paper and other
industries for hydraulic, steam pressure, steam delivery and other soft
connectors.
1.4, PTFE spiral tube
PTFE spiral tube, also known as PTFE
flexible hose, has flexible properties in addition to all the excellent
properties of PTFE. At present, there are two types of pure PTFE spiral tubes
and chemical fibers, stainless steel wires and plastic coated glass fibers.
It is
made by PTFE whole secondary processing, which is made by continuously rotating
the PTFE thin-walled tube continuously through a combined mold with a
temperature of 270 °C ~ 280 °C at a certain speed.
It is
mainly used for the connection of the flexible connection of the
corrosion-resistant and high-temperature resistant equipment, the misalignment
connection, the serpentine pipeline, the pump engine and other shocking
components. Shielded cables and protective cable bushings for aircraft engines.
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